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Reaction Engineering, Kinetics and Catalysts,
Kinetic, mechanistic and thermodynamic investigations on Iridium (III) catalyzed oxidation of D-Mannitol by N-chloro-p-toluenesulfonamide in perchloric acid medium

J. Pandey; A. Verma; R. Patel; Sh. Srivastava

Volume 14, Issue 4 , December 2017, , Pages 77-89

Abstract
  The present paper deals with the kinetics and mechanism of homogeneously Ir(III) chloride catalyzed oxidation of D-mannitol by chloramine-T [CAT] in perchloric acid medium in the temperature range of 30 to 45 0C. The reaction is carried out in the presence of mercuric acetate as a scavenger for chloride ...  Read More